Ferrous chloride tetrahydrate

Section 1: Chemical Product and Company Identification

Product Name: Ferrous chloride tetrahydrate

CAS#: 13478-10-9

Supplier: KINFON PHARMACHEM CO.,LTD

F4, No.5 Torch Ave, JLP Dist, Chongqing 400080, China

website: www.echemix.com     email: sales@echemix.com

Section 2: Composition and Information on Ingredients

Name                             CAS #              Synonyms

Ferrous chloride tetrahydrate               13478-10-9          Iron(II) chloride tetrahydrate

Section 3: Hazards Identification

EMERGENCY OVERVIEW

Appearance: light green solid.
Caution! May cause respiratory tract irritation. May cause severe eye and skin irritation with possible burns. May cause severe digestive tract irritation with possible burns. Air sensitive. Hygroscopic (absorbs moisture from the air). The toxicological properties of this material have not been fully investigated.
Target Organs: Kidneys, central nervous system, liver.

Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: Exposure may cause irritation and possible burns.
Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Acute exposure to excessive levels of ferrous compounds can cause liver and kidney damage. May cause CNS irritation. Iron compounds cause hemorrhage and necrosis of the stomach with shock, severe diarrhea and possible coma. Delayed symptoms such as acidosis, shock, rapid breathing, liver injury and possible death may occur.
Inhalation: May cause respiratory tract irritation.
Chronic: Chronic ingestion may cause effects similar to those of acute ingestion.

Section 4: First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.

Section 5: Fire and Explosion Data

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1

Section 6: Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7: Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

OSHA Vacated PELs: Iron (II) chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9: Physical and Chemical Properties

Physical State: Solid
Appearance: light green
Odor: Not available.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 693 deg
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:> 150 deg C
Solubility: 1600g/l (10°C) in H2O
Specific Gravity/Density:Not available.
Molecular Formula:FeCl2.4H2O
Molecular Weight:198.8066

Section 10: Stability and Reactivity Data

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials: Ethylene oxide, potassium,sodium, strong oxidizing agents, ozonides, metal halides..
Hazardous Decomposition Products: Hydrogen chloride, oxides of iron.
Hazardous Polymerization: Will not occur.

Section 11: Toxicological Information

RTECS#:     
CAS# 13478-10-9: NO5600000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 13478-10-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12: Ecological Information

Ecotoxicity: No data available. Water danger/protection: WGK1
Environmental: No information available.
Physical: No information available.
Other: No information available.

Section 13: Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14: Transport Information

Section 15: Other Regulatory Information

US FEDERAL

TSCA
     CAS# 13478-10-9 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 13478-10-9: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 13478-10-9 can be found on the following state right to know lists: California, (listed as Iron salts (soluble)), Pennsylvania, (listed as Iron salts (soluble)), Minnesota, (listed as Iron salts (soluble)).
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:
     R 22 Harmful if swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
     CAS# 13478-10-9: 1
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 13478-10-9 (listed as Iron salts (soluble)) is listed on the Canadian Ingredient Disclosure List.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge. And above information is only for reference.